A NbO-type metal-organic framework derived from a polyyne-coupled di-isophthalate linker formed in situ

作者：Zhao Dan; Yuan Daqiang; Yakovenko Andrey; Zhou Hong Cai^*

来源：Chemical Communications, 2010, 46(23): 4196-4198.

DOI：10.1039/c002767g

A NbO-type metal-organic framework, PCN-46, was constructed based on a polyyne-coupled di-isophthalate linker formed in situ. Its lasting porosity was confirmed by N(2) adsorption isotherm, and its H(2), CH(4) and CO(2) adsorption capacity was examined at 77 K and 298 K over a wide pressure range (0-110 bar).

• 出版日期2010