The enthalpy of formation of gaseous tetra-n- propylammonium cations

作者：Marcus Yizhak^*

来源：Journal of Chemical Thermodynamics, 2014, 71: 196-199.

DOI：10.1016/j.jct.2013.12.007

• Enthalpy of formation of crystalline salts
• Lattice energy
• Enthalpy of formation of gaseous cation
• Tetraalkylammonium cations
• Enthalpy of hydration

The standard molar enthalpies of formation of crystalline tetraalkylammonium halides, Delta H-f degrees(R4NX, c), R = Me, Et, Pr, Bu and X = Cl, Br, I, and the corresponding lattice energies, U-L(R4NX) were obtained from the literature as far as available for T = 298.15 K. From consistent values of these two quantities and values for Delta H-f degrees( X , g) the standard molar enthalpies of formation of the gaseous cations were obtained from Delta H-f degrees(R4N+, g) = Delta H-f degrees(R4NX, c) + U-L( R4NX) + 2RT degrees - Delta H-f degrees(X , g). The value for the hitherto unreported Delta Hf-degrees (Pr4N+, g) = ( 307 +/- 7) kJ center dot mol is here derived. The value for the absolute standard molar enthalpy of hydration Delta H-h degrees(R4N+, aq) is-210 kJ center dot mol (1), but may have an appreciable uncertainty, reflecting that of Delta H-f degrees(R4N+, aq), obtained from interpolation of values for the Me, Et, and Bu analogues.

• 出版日期2014-4