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摘要
When a phase-separated binary (A + B) mixture is exposed to a wall, that preferentially attracts one of the components, interfaces between A-rich and B-rich domains in general meet the wall making a contact angle theta. Young's equation describes this angle in terms of a balance between the A-B interfacial tension gamma(AB) and the surface tensions gamma(wA), gamma(wB) between, respectively, the A- and B-rich phases and the wall, gamma(AB)cos theta = gamma(wA) - gamma(wB). By Monte Carlo simulations of bridges, formed by one of the components in a binary Lennard-Jones liquid, connecting the two walls of a nanoscopic slit pore, theta is estimated from the inclination of the interfaces, as a function of the wall-fluid interaction strength. The information on the surface tension difference gamma(wA) - gamma(wB) are obtained independently from a new thermodynamic integration method, while gamma(AB) is found from the finite-size scaling analysis of the concentration distribution function. We show that Young's equation describes the contact angles of the actual nanoscale interfaces for this model rather accurately and the location of the (first-order) wetting transition is estimated.
- 出版日期2010-10
