Hydrothermal synthesis and characterization of an Mn(II) coordination polymer with 3,3 '-bpdc center dot H2O as ligand

作者：Holynska Malgorzata^*; Kolodziejczak Jerzy; Kochel Andrzej

来源：Inorganica Chimica Acta, 2015, 436: 214-219.

DOI：10.1016/j.ica.2015.08.001

• Coordination polymer
• Manganese(II)
• Magnetic properties
• Topological analysis

The new 2D coordination polymer with a new 3,3'-bipyridine-2,2'-dicarboxylate monohydrate (3,3'-bpdc center dot H2O) ligand is described: [Mn(3,3'-bpdc)](n). In the distorted octahedral coordination environment of the Mn2+ cations the 3,3'-bptc ligand is bonded through nitrogen/carboxylate oxygen atoms. The [Mn(3,3'-bpdc)](n) polymer is characterized by X-ray diffraction studies, IR spectra, elemental analysis, TGA, magnetic properties measurements and the Atoms-in-Molecules analysis of the electron density.

• 出版日期2015-9-1