Molecular Scissoring: Facile 3D to 2D Conversion of Lanthanide Metal Organic Frameworks Via Solvent Exfoliation

作者:Quah Hong Sheng; Ng Li Ting; Donnadieu Bruno; Tan Geok Kheng; Vittal Jagadese J*
来源:Inorganic Chemistry, 2016, 55(21): 10851-10854.
DOI:10.1021/acs.inorgchem.6b02222

摘要

Five lanthanide MOFs with pcu topology have been exfoliated into nanoplatelets of two-dimensional structures via sonication in the dimethylacetamide solvent. These nanosheets are fluorescent under two-photon excitation dominated by the ligand, indicating energy upconversion ability.

  • 出版日期2016-11-7