A one-pot stereoselective synthesis of 1,4-dienyl selenides by hydrostannylation-Stille tandem reaction of acetylenic selenides with Bu3SnH and allylic bromides

作者：Yu La Mei; Hao Wen Yan; Cai Ming Zhong^*

来源：Chinese Chemical Letters, 2008, 19(9): 1047-1050.

DOI：10.1016/j.cclet.2008.06.029

• Acetylenic selenide
• Hydrostannylation
• Stille coupling
• 1,4-Dienyl selenide
• Stereoselective synthesis

1,4-Dienyl selenides can be stereoselectively synthesized in one pot under mild conditions in good yields by the palladium-catalyzed hydrostannylation of acetylenic selenides, followed by Stille coupling with allylic bromides.

• 出版日期2008-9
• 单位江西师范大学