Application of Polycarbonate Diol Prepared with Carbon Dioxide in the Field of Waterborne Polyurethane

作者：Lim Jae Woo; Oh Hyoung Jin; Kim Youngjo; Jeong Kwang Eun; Yim Jin Heong^*; Ko Young Soo

来源：Polymer-Korea, 2010, 34(6): 507-510.

• polyurethane
• poly(hexamethylene carbonate) glycol
• poly(caprolactone) glycol
• carbon dioxide

Poly(cyclohexane carbonate) diol was synthesized by the alternating copolymerization of cyclohexene oxide and CO(2) over Cr based transition metal catalysts. The prepared PCCD was applied as a precursor for the preparation of waterborne polyurethane (PUD) in order to investigate an application field of carbon dioxide-based polycarbonate. The scratch resistance and thermal properties of PUDs, which was prepared with two kinds of polymeric diols (PCD and PCCD) were investigated. The scratch resistance and thermal decomposition temperature of PUD film prepared with PCCD is worse than those prepared with PCD, poly (hexamethylene carbonate) glycol. While, glass transition temperature of PUD film prepared with PCCD was higher than that prepared with PCD. It might be due to the rigid cyclohexane structure in the PCCD.

• 出版日期2010-11