mu-aqua-bis(mu-4-chlorobenzoato)bis[(4-chlorobenzoato)(1,10-phenanthroli ne)manganese(II)]

作者：Shen, Yu-Li; Sun, Sheng-Li; Song, Wen-Dong^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M1309-M1311.

DOI：10.1107/S1600536807017801

• single-crystal X-ray study
• T=293 K
• mean sigma(C-C)=0.006 angstrom
• R factor=0.045
• wR factor=0.122
• data-to-parameter ratio=14.9

The title complex molecule, [Mn-2(C7H4ClO2)(4)(C12H8N2)(2)-( H2O)], possesses crystallographically imposed C-2 symmetry. Each Mn-II atom is coordinated by three carboxyl O atoms from three 4-chlorobenzoate ligands, two N atoms from one 1,10-phenanthroline ligand and one bridging water molecule in a distorted octahedral coordination geometry. The Mn . . . Mn separation is 3.512 (3) angstrom. Symmetrically related dinuclear molecules form chains parallel to the c axis via pi-pi stacking interactions.

• 出版日期2007-5
• 单位广东海洋大学