Determination of SBA-15 acidity through n-butyl amine TPD: a theoretical and experimental study

作者:Luz Geraldo E Jr*; Lima Francisco C A; Costa Neto Cicero O; Paz Gizeuda L; Silva Edjane F B; Barbosa Marcela N
来源:Journal of Materials Science, 2013, 48(20): 6885-6890.
DOI:10.1007/s10853-013-7492-5

摘要

In this study, the interaction ways between n-butyl amine and SBA-15 molecular sieve were evaluated when the TPD technique is carried out to determine the total acidity of that solid. Experimental results (FTIR, TG/DTG, total acid, and catalytic activity) and theoretical calculations demonstrated that the n-butyl amine, used as probe molecule to total acidity determined by TPD, can act as acid or base depending on the nature and force of the active sites on SBA-15.

  • 出版日期2013-10

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