A semi-flexible aminotriazine-based bis-methylpyridine ligand for the design of nickel(II) spin clusters

作者：Tzeng Yen Wen; Lin Chang Jui; Nakano Motohiro; Yang Chen I^*; Wan Wun Long; Lai Long Li

来源：Dalton Transactions, 2014, 43(8): 3044-3047.

DOI：10.1039/c3dt52903g

The self-assembly of a semi-flexible aminotriazine-based bis-methylpyridine ligand, N-2,N-2-dibenzyl-N-4,N-6-di(pyridylmethyl)1,3,5-triazine-2,4,6-triamine (H2L), with NiCl2 and NiBr2 afforded two new nickel(II) clusters, (H2NMe2) (2)[Ni-5(OH)(2)(H2L)(2)Cl-10] (1) and [Ni-6(OH)(2)(H2L)(2)Br-10(THF)(2)] (2) showing a high spin ground state of S = 3.

• 出版日期2014