A red fluorophore comprising a borinate-containing xanthene analogue as a polyol sensor

作者:Shimomura N; Egawa Y*; Miki R; Fujihara T; Ishimaru Y; Seki T
来源:Organic and Biomolecular Chemistry, 2016, 14(42): 10031-10036.
DOI:10.1039/c6ob01695b

摘要

A xanthene derivative containing a borinate moiety emitted red fluorescence with a high quantum yield. The interaction between the borinate and a sugar molecule induced a fluorescence change based on the change in the HOMO-LUMO gap. The response was pH-resistant in a wide range. In addition, catechol quenched through photoinduced electron transfer. The red fluorescence and polyol binding ability of dyes will pave the way for new biological applications of chemical sensors.

  • 出版日期2016