A Mixed-Cluster Approach for Building a Highly Porous Cobalt(II) Isonicotinic Acid Framework: Gas Sorption Properties and Computational Analyses

作者：Chen, Di-Ming; Zhang, Nan-Nan; Liu, Chun-Sen^*; Jiang, Zhi-Hao; Wang, Xing-Dong; Du, Miao^*

来源：Inorganic Chemistry, 2017, 56(5): 2379-2382.

DOI：10.1021/acs.inorgchem.6b03170

• METAL-ORGANIC FRAMEWORK
• CO-II
• COORDINATION FRAMEWORKS
• SELECTIVE SORPTION
• HYDROGEN STORAGE
• H-2
• SEPARATION
• CRYSTAL
• CAPTURE
• LINKER

A unique channel-type metal-organic framework (MOF) built up from mixed square-planar Co-4(mu(2)-OH)(4)(mu(4)-OH) and cuboidal Co-4(mu(3)-OH)(4) clusters with an isonicotinic acid ligand has been successfully fabricated that demonstrates the highest specific surface area and high H-2 uptake capacities among all of the cobalt(II) isonicotinic acid frameworks reported so far.

• 出版日期2017-3-6
• 单位郑州轻工业大学