摘要

[Co-2(bdC)(2)(ted)]center dot 2DMF center dot 3H(2)O (2), (DMF = N,N'-dimethylformamide, bdc = 1,4-benzenedicarboxylate dianion, ted = triethylenediamine) was prepared and characterized by IR, elemental analysis, TGA, powder X-ray analysis and single-crystal X-ray determination. At ambient temperature the material [Co-2(bdC)(2)(ted)] (1) was found to be high adsorbent or methane but poor adsorbent of hydrogen.