Autonomic restoration of electrical conductivity using polymer-stabilized carbon nanotube and graphene microcapsules

作者:Odom Susan A; Tyler Timothy P; Caruso Mary M; Ritchey Joshua A; Schulmerich Matthew V; Robinson Scott J; Bhargava Rohit; Sottos Nancy R; White Scott R; Hersam Mark C*; Moore Jeffrey S
来源:Applied Physics Letters, 2012, 101(4): 043106.
DOI:10.1063/1.4737935

摘要

We report the use of microcapsules containing suspensions of polymer-stabilized carbon nanotubes and/or graphene flakes for the autonomic restoration of conductivity in fractured gold lines. Multilayered samples were prepared in which microcapsules were embedded in layers of epoxy above and below a glass slide patterned with gold lines. Upon sample fracture, conductivity was lost as a crack formed in the gold line. Simultaneous release of carbon nanotubes and/or graphene suspensions from capsule cores restored conductivity in minutes. We suggest a healing mechanism in which the released carbon nanomaterials bridge gaps in the gold lines.