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摘要
A scandium complex based on a new type of tridentate ligand enabled an atom- and step-economical C(sp(3))-H addition of N, N-dimethyl anilines to a variety of unactivated alkenes affording branched products for the first time. A cationic o-dimethylaminophenyl scandium species was isolated and confirmed as the catalytic intermediate in this transformation.
- 出版日期2018-1
- 单位苏州大学
