A sulfur rich electron acceptor and its [Fe(Cp*)(2)](+) charge transfer salt with ferromagnetic interactions

作者:Le Gal Yann; Bellec Nathalie; Barriere Frederic; Clerac Rodolphe; Fourmigue Marc; Dorcet Vincent; Roisnel Thierry; Lorcy Dominique*
来源:Dalton Transactions, 2013, 42(48): 16672-16675.
DOI:10.1039/c3dt52725e

摘要

The study of a side product of the aerial dithiolene oxidation allowed the rational and efficient synthesis of a sulfur rich electron acceptor, (E)-3,3%26apos;-diethyl-5,5%26apos;-bithiazolidinylidene-2,4,2%26apos;, 4%26apos;-tetrathione, that presents easily accessible redox states and forms with decamethylferrocene a charge transfer salt exhibiting ferromagnetic coupling.

  • 出版日期2013