Ascorbic acid decomposition into oxalate ions: a simple synthetic route towards oxalato-bridged heterometallic 3d-4f clusters

作者:Dinca Alina S; Shova Sergiu; Ion Adrian E; Maxim Catalin; Lloret Francesc; Julve Miguel; Andruh Marius*
来源:Dalton Transactions, 2015, 44(16): 7148-7151.
DOI:10.1039/c5dt00778j

摘要

Two types of oxalato-bridged heterometallic 3d-4f dodeca- and hexanuclear compounds have been obtained by connecting six bi-and, respectively, trinuclear moieties through oxalato bridges arising from the slow decomposition of the L-ascorbic acid.

  • 出版日期2015