Nanospherical-Like Manganese Monoxide/Reduced Graphene Oxide Composite Synthesized by Electron Beam Radiation as Anode Material for High-Performance Lithium-Ion Batteries

作者：Jiang, Xiaoyu; Zhu, Xiaoming; Liu, Xiaoling; Xiao, Lifen; Ai, Xinping; Yang, Hanxi; Cao, Yuliang^*

来源：Electrochimica Acta, 2016, 196: 431-439.

DOI：10.1016/j.electacta.2016.02.164

• manganese monoxide
• graphene
• lithium-ion battery
• electron beam radiation

Nanospherical-like manganese monoxide/reduced graphene oxide (MnO/rGO) nanocomposites are synthesized by using an electron beam radiation approach in an aqueous solution containing potassium permanganate and graphene oxide in the presence of acetone as radical scavenger and subsequently calcining in flowing Ar atmosphere. SEM and TEM observations show that nanospherical-like MnO with average size of 20 nm are firmly anchored onto the rGO to form MnO/rGO nanocomposites. The typical MnO/rGO nanocomposite exhibits a high initial reversible capacity (977.1 mAh g(-1)) at a current density of 150 mA g(-1) and delivers 648.4 mAh g(-1) at a rate of 750 mAh g(-1) with excellent cycling performance (89% of capacity retention over 50 cycles), which indicates that the MnO/rGO nanocomposite is a promising anode candidate for Li-ion batteries. Furthermore, the facile synthetic strategy by using an electron beam radiation provides a novel avenue for making high-performance metal oxide/graphene nanocomposites for energy storage applications.

• 出版日期2016-4-1
• 单位湖北科技学院; 武汉大学; 华中师范大学