A series of zirconium-oxo cluster complexes based on arsenate or phosphonate ligands

作者：Chen, Guang-Hui; He, Yan-Ping^*; Zhang, Shu-Hua^*; Zhang, Lei

来源：Inorganic Chemistry Communications, 2018, 97: 125-128.

DOI：10.1016/j.inoche.2018.09.013

• Zirconium-oxo clusters
• Arsenate/phosphonate ligands
• Syntheses
• Structures

A series of zirconium-oxo cluster complexes have been prepared by the reaction of Zr(OnPr)(4) and arsenate or phosphonate ligands, namely, Zr-6(mu(3)-O)(2)(4-aPhaa)(4)(OnPr)(12) (Zr-6-1, 4-aPhaa = 4-aminophenylarsonic acid), Zr-6(mu(3)-O)(2)(tbpa)(4)(OnPr)(12) (Zr-6-2, tbpa = tert-butylphosphonic acid), H-2[Zr-6(mu(3)-O)(tbpa)(5)(OnPr)(12)] (Zr-6-3), and H-4[Zr-10(mu(4)-O)(4)(mu(3)-O)(4)(PPa)(4)(OnPr)(20)] (Zr-10, ppa = phenylphosphonic acid). These complexes have been structurally characterized by the single-crystal X-ray diffraction. Interestingly, the {Zr-10} cluster contains a [Zr10O4](32+) supertetrahedron core stabilized by the phosphate groups. In addition, thermal stabilities and phase purities were also investigated in detail.

• 出版日期2018-11
• 单位中国科学院福建物质结构研究所; 结构化学国家重点实验室; 桂林理工大学