Achieving high efficiency Cu2ZnSn(S,Se)(4) solar cells by non-toxic aqueous ink: Defect analysis and electrical modeling

作者：Wei Shih Yuan; Liao Yueh Chun; Hsu Chia Hao; Cai Chung Hao; Huang Wei Chih; Huang Mao Cheng; Lai Chih Huang^*

来源：Nano Energy, 2016, 26: 74-82.

DOI：10.1016/j.nanoen.2016.04.059

• Kesterite
• CZTSSe
• Non-toxic
• Aqueous ink
• Electrical properties

An extremely environment-friendly aqueous-ink process for Cu2ZnSn(S,Se)(4) (CZTSSe) fabrication is reported. The aqueous ink is composed of SnSx nanoparticles, zinc ions from zinc nitrate (Zn(NO3)(2)), and metal complex made of copper nitrate (Cu(NO3)(2)) and thioacetamide (C2H5NS). The combinations of negatively surface-charged SnSx nanoparticles and cations form electric double layers and lead to a well mixed and dispersed aqueous CZTSSe precursor ink, which eliminates the usage of hazard solvent. The results of X-ray diffraction, Raman spectroscopy, scanning electron microscope, and auger electron spectroscopy show that the CZTSSe film possesses a single phase, good crystallinity, and uniform composition after an annealing process. A high cell efficiency of 10.05% is achieved by using this novel aqueous-ink approach. To further investigate the possible root cause of efficiency limitation, the electrical properties of CZTSSe cells are studied. The existence of deep donor defects, which results in low carrier concentration as well as collapsed short-circuit current and fill factor at low temperature, is proposed. Our proposed model suggests that the relatively deep p-type defects (Cum) as the major carrier source, the existence of deep n-type defects and short diffusion length are the key limitations for achieving high efficiency of CZTSSe solar cells.

• 出版日期2016-8
• 单位清华大学