A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage

作者：Long De Liang^*; Yan Jun; de la Oliva Andreu Ruiz; Busche Christoph; Miras Haralampos N; Errington R John; Cronin Leroy

来源：Chemical Communications, 2013, 49(84): 9731-9733.

DOI：10.1039/c3cc45659e

The new tungstatoiodate, alpha-[H5W18O59(IO3)](6-), containing IVO3- within a {W18O54} metal oxide framework has been prepared and shown by X-ray crystallography and mass spectrometry to be derived from the fully oxidised [H3W18O56(IO6)](6-) by two-electron reduction accompanied by a redox-triggered structural rearrangement where three I-O covalent bonds are broken.

• 出版日期2013