Bismuth(III) Oxide Catalyzed Oxidation of Alcohols with tert-Butyl Hydroperoxide

作者：Malik Payal; Chakraborty Debashis^*

来源：Synthesis (Germany), 2010, 2010(21): 3736-3740.

DOI：10.1055/s-0030-1258221

• oxidations
• alcohols
• Bi(2)O(3)
• t-BuOOH
• reaction rates

A variety of aromatic, aliphatic and conjugated alcohols were transformed into the corresponding carboxylic acids and ketones with aq 70% t-BuOOH in the presence of catalytic amounts of bismuth(III) oxide. This method possesses a wide range of capabilities, does not involve cumbersome work-up, exhibits chemoselectivity and proceeds under ambient conditions. The resulting products are obtained in good yields within reasonable time. The overall method is green.

• 出版日期2010-11