mu-oxido-bis({4,4 '-dibromo-2,2 '-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato} manganese(III))

作者：Liu Ying^*; Dou Jianmin; Niu Meiju; Zhang Xianxi

来源：Acta Crystallographica Section E-Structure Reports Online, 2007, 63(11): M2771-U1298.

DOI：10.1107/S1600536807051008

The title compound, [Mn-2(C16H12Br2N2O2)(2)O], is an unusual dinuclear manganese(III) complex. Each Mn-III ion has a distorted square-pyramidal coordination geometry. In the basal plane, the Mn atom is coordinated by two N atoms and two O atoms of the Schiff base ligand. The apical position is occupied by a bridging O2- ion, which links to the other Mn-III ion in the complex; this bridging O atom lies on a twofold rotation axis.

• 出版日期2007-11
• 单位聊城大学