A photoswitchable rotaxane operating in monolayers on solid support

作者:Schwarz Felix B; Heinrich Thomas; Lippitz Andreas; Unger Wolfgang E S*; Schalley Christoph A*
来源:Chemical communications, 2016, 52(100): 14458-14461.
DOI:10.1039/c6cc08586e

摘要

A novel photoswitchable rotaxane was synthesised and its switching behaviour in solution was analysed with NMR and UV-Vis. A monolayer of rotaxanes was deposited on glass surfaces and the on-surface photoswitching was investigated. Angle-resolved NEXAFS spectra revealed a preferential orientation that reversibly changes upon switching.

  • 出版日期2016