Mechanically stable, hierarchically porous Cu-3(btc)(2) (HKUST-1) monoliths via direct conversion of copper(II) hydroxide-based monoliths

作者：Moitra Nirmalya; Fukumoto Shotaro; Reboul Julien; Sumida Kenji; Zhu Yang; Nakanishi Kazuki; Furukawa Shuhei; Kitagawa Susumu; Kanamori Kazuyoshi^*

来源：Chemical Communications, 2015, 51(17): 3511-3514.

DOI：10.1039/c4cc09694k

The synthesis of highly crystalline macro-meso-microporous monolithic Cu-3(btc)(2) (HKUST-1; btc(3-) = benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH)(2)-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.

• 出版日期2015