科研之友
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摘要
A 3D chiral microporous metal-organic framework containing a nonanuclear cluster as a secondary building unit was prepared using a bent and rigid dicarboxylic ligand, 2,7-naphthalene dicarboxylic acid, and the zinc ion, where a nonanuclear cluster with potential exposed metal sites is in the form of a corner-sharing cyclic trimer of a tetrahedral Zn(4)O motif.
- 出版日期2009
