A ketone oximate based cyclic cationic [Ni-4(II)] inverse metallacrown from simultaneous chelation and bridging of two ligands

作者:Mandal Debashree; Bertolasi Valerio; Aromi Guillem; Ray Debashis*
来源:Dalton Transactions, 2007, (20): 1989-1992.
DOI:10.1039/b704678m

摘要

The Ni-4 inverse metallacrown (NHEt3) [Ni-4(bmo)(4)(Hael)(2)-(ael)(2)](ClO4)(3) [(NHEt3)center dot 1 center dot(ClO4)(3)], with the inverse 12-MC-4 motif, has been assembled via simultaneous chelation and bridging of butan-2,3-dionemonoxime (Hbmo) and 2-amino ethanol (Hael).

  • 出版日期2007