Azolium azolates from reactions of neutral azoles with 1,3-dimethyl-imidazolium-2-carboxylate, 1,2,3-trimethyl-imidazolium hydrogen carbonate, and N,N-dimethyl-pyrrolidinium hydrogen carbonate

作者：Smiglak Marcin; Hines C Corey; Reichert W Matthew; Shamshina Julia L; Beasley Preston A; McCrary Parker D; Kelley Steven P; Rogers Robin D^*

来源：New Journal of Chemistry, 2013, 37(5): 1461-1469.

DOI：10.1039/c3nj00147d

Utilizing previously reported synthetic protocols for the halide-and metal-free synthesis of organic salts, we have prepared a new group of imidazolium and pyrrolidinium azolate anion-based salts demonstrating the general applicability of the methodology and expanding our investigation into non ion exchange routes to potentially energetic ionic liquids. Eighteen salts, out of which six exhibit melting points below 100 degrees C, were prepared by a simple decarboxylation reaction, which resulted in clean formation of the new compounds without the need for extensive purification. The low stability of the H2CO3 by-product, and its decomposition to CO2 and H2O in aqueous media, allows for purification of the salts by evaporation only.

• 出版日期2013