Discrete and infinite metal-organometallic coordination networks consisting of europium(III) nodes and quinone pi-complexes as spacers

作者：Reingold JA; Jin MZ; Sweigart DA^*

来源：Inorganica Chimica Acta, 2006, 359(6): 1983-1987.

DOI：10.1016/j.ica.2005.12.033

• coordination networks
• europium
• lanthanides
• quinonoid
• organometalloligand

The reaction of the organometalloligand [(eta(4)-benzoquinone)Mn(CO)(3)](-) (p-QMTC) with Eu3+ nodes has been utilized to generate the discrete and polymeric supramolecular metal-organometallic coordination networks [Eu(DMSO)(NO3)(2)(p-QMTC)(2)](2) (1) and the polymeric [Eu(p-QMTC)(3)](infinity) (2). The X-ray structures of I and 2 are reported.

• 出版日期2006-4-10