An efficient metal-free sensitizer for dye-sensitized solar cells

作者:Tsao, Ming Hsiu; Wu, Tzi Yi*; Wang, Hong Paul; Sun, I Wen; Su, Shyh Gang; Lin, Yuan Chung; Chang, Cheng Wen
来源:Materials Letters, 2011, 65(3): 583-586.
DOI:10.1016/j.matlet.2010.10.072

摘要

A novel metal-free organic dye consisting of a phenothiazine donor, a 3,4-ethylenedioxythiophene bridge, and a cyanoacrylate acceptor is synthesized and its optical, electrochemical and photovoltaic properties are characterized. A solar cell employing the metal-free dye exhibits a maximum solar energy to an electricity conversion efficiency of 6.72% under AM 1.5 solar simulator (100 mW cm(-2)). The results suggest that dye based on a phenothiazine donor and 3,4-ethylenedioxythiophene pi-spacer is a promising candidate for high performance dye-sensitized solar cells.