A Copper-Catalyzed Azide-Alkyne Cycloaddition Approach to the Synthesis of Bimetallic Chromium(0) (Fischer) Carbene Complexes

作者:Baeza Beatriz; Casarrubios Luis*; Ramirez Lopez Pedro; Gomez Gallego Mar; Sierra Miguel A
来源:Organometallics, 2009, 28(4): 956-959.
DOI:10.1021/om801171x

摘要

The Cu(I)-catalyzed 1,3-dipolar cycloaddition of bis-azides to alkynyl chromium(0) (Fischer) carbene complexes has been developed. The method is a new entry to the synthesis of highly functionalized chromium(0) bis-carbene complexes bearing different tethers joining both metal centers.

  • 出版日期2009-2-23