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摘要
A new synthesis of [3]ferrocenophan-1-one has been developed, and a Trofimov reaction has been applied to its ketoxime. The novel subsequent N-vinyl pyrrole ferrocenophane displays reversible electrochemical behavior centered on the ferrocene, without any participation of the pyrrole. Unexpected byproduct was also isolated, in which the a-pyrrolic position is methylated.
- 出版日期2011-12-12
