A 6(3)-Nets Framework Constructed by Cadmium(II) Hexafluorosilicate and 3-(Pyridin-4-yl)benzenamine: Synthesis, Structure, and Luminescence Property

作者：Qi, De-Qiang; Hou, Gui-Ge^*; Wang, Xue-Jie; Zhang, Yi-Ping; You, Jin-Zong

来源：Synthesis and Reactivity in Inorganic Metal-Organic and Nano-Metal Chemistry, 2015, 45(3): 407-410.

DOI：10.1080/15533174.2013.841206

• structure
• luminescence property
• metal-organic framework
• 6(3)-nets

A novel 6(3)-nets framework {[Cd(SiF6)(C11H10N2)(2)]center dot(CH2Cl2)center dot(H2O)}(n) (1) was generated based on asymmetric ligand 3-(pyridin-4-yl)benzenamine (L). L acts as a bidentate ligand to link Cd(II) centers into a 6(3)-nets topology with rectangular channels encapsulating dichloromethane and water as guest molecules. In addition, their luminescent properties were investigated primarily in the solid state, which is basically related to its incorporation into the metal-containing complexes. The result displays that the choice of the amino-functionalized pyridine-containing ligand leading to special connection patterns and diversity of the hydrogen bonds plays a crucial role in the construction of the novel topological framework with interesting luminescent property.

• 出版日期2015-3-4
• 单位浙江外国语学院; 滨州医学院