Allylic borylation of tertiary allylic alcohols: a divergent and straightforward access to allylic boronates

作者：Harada Kohei; Nogami Marina; Hirano Keiichi^*; Kurauchi Daisuke; Kato Hisano; Miyamoto Kazunori; Saito Tatsuo; Uchiyama Masanobu^*

来源：Organic Chemistry Frontiers, 2016, 3(5): 565-569.

DOI：10.1039/c6qo00009f

A facile and divergent synthetic process for converting tertiary allylic alcohols to multiply substituted allylic boronates is reported. This methodology is especially effective for tertiary alcohol substrates, providing the corresponding allylic boronates in moderate to good yields.

• 出版日期2016