A structural and H-1 NMR relaxometric study on novel layered carboxyalkylaminophosphonate nanocrystals with Gd(III) ions located in the framework

作者:Scafuri Antonio; Vivani Riccardo; Carniato Fabio; Tei Lorenzo; Botta Mauro*; Taddei Marco; Costantino Ferdinando
来源:Dalton Transactions, 2015, 44(44): 19072-19075.
DOI:10.1039/c5dt02808f

摘要

Novel Gd(III) carboxyalkylphosphonate nanocrystals were synthesized under mild hydrothermal conditions. Structural properties and H-1 NMR relaxometric behaviour in aqueous solution as a function of the magnetic field strength were investigated, aiming to evaluate the local chemical environment of the paramagnetic centres and their interaction and affinity with water molecules.

  • 出版日期2015
  • 单位Perugia