Nickel N-Heterocyclic Carbene Catalyst for Cross-Coupling of Neopentyl Arenesulfonates with Methyl and Primary Alkyl Grignard Reagents

作者：Kim Chul Bae; Jo Hyunjong; Ahn Bo Kyoung; Kim Chang Keun; Park Kwangyong^*

来源：Journal of Organic Chemistry, 2009, 74(24): 9566-9569.

DOI：10.1021/jo902151h

Nickel N-heterocyclic carbene (NHC) catalytic system prepared in Situ by the reaction of Ni(acac)(2) with NHC precursor efficiently catalyzed the cross-coupling reaction of alkoxysulfonylarenes with methyl, neopentyl, and benzyl Grignard reagents at ambient temperature.

• 出版日期2009-12-18