A new Pu(III) coordination geometry in (C5H5NBr)(2)[PuCl3(H2O)(5)].2Cl.2H(2)O as obtained via supramolecular assembly in aqueous, high chloride media

作者：Surbella Robert G III; Ducati Lucas C; Pellegrini Kristi L; McNamara Bruce K; Autschbach Jochen; Schwantes Jon M; Cahill Christopher L^*

来源：Chemical Communications, 2017, 53(78): 10816-10819.

DOI：10.1039/c7cc05988d

Crystals of a hydrated Pu(III) chloride, (C5H5NBr)(2)[PuCl3(H2O)(5)].2Cl.2H(2)O, were grown via slow evaporation from acidic aqueous, high chloride media. X-ray diffraction data reveals the neutral [PuCl3(H2O)(5)] tecton is assembled via charge assisted hydrogen and halogen bonds donated by 4-bromopyridiniumcations and a series of inter- tecton hydrogen bonds.

• 出版日期2017-10-7