Photophysical, photochemical and laser behavior of some diolefinic laser dyes in sol-gel and methyl methacrylate/2-hydroxyethyl methacrylate copolymer matrices

作者：Sakr Mahmoud A S; Gawad El Sayed A Abdel; Abou Kana Maram T H; Ebeid El Zeiny M^*

来源：Optics and Laser Technology, 2015, 71: 78-84.

DOI：10.1016/j.optlastec.2015.02.008

• Diolefinic laser dyes
• Sol-gel host matrix
• Copolymer matrix
• Photostability

The photophysical properties such as singlet absorption, molar absorptivity, fluorescence spectra, dipole moment, fluorescence quantum yields, fluorescence lifetimes and laser activity of 1,4-bis (beta-Pyridyl-2-Vinyl) Benzene (P2VB), 2,5-distyryl-pyrazine (DSP) and 1,4-bis(2-methylstyryl)benzene(MSB) diolefineic laser dyes have been measured in different restricted hosts. (P2VB). (DSP) and (MSB) are embedded in transparent sol-gel glass and a copolymer of methyl methacrylate (MMA) and 2-hydroxyethyl methacrylate (HEMA) media. The absorption and fluorescence properties of these laser dyes in sot-gel glass matrices are compared with their respective properties in copolymer host. The photostability of these laser dyes in sol-gel glass and (MMA/HEMA) copolymer samples are measured in terms of half-life method (using nitrogen laser 337.1 nm in pumping), as the number of pulses necessary to reduce the dye laser intensity to 50% of its original value. The gel laser materials show improved photostability upon pumping by nitrogen laser compared with those in organic polymeric host matrix.

• 出版日期2015-8