Azide ion recognition in water-CHCl3 using a chelating phosphonium borane as a receptor

作者：Kim Youngmin; Hudnall Todd W; Bouhadir Ghenwa; Bourissou Didier^*; Gabbai Francois P

来源：Chemical communications, 2009, (25): 3729-3731.

DOI：10.1039/b905232a

In H2O-CHCl3, the phosphonium borane [ortho-(Mes(2)B)C6H4(PMePh2)]( ) selectively complexes azide anions to afford ortho-(Mes(2)(N-3)B)C6H4(PMePh2) in which the boron-bound azide anion is stabilized by an interaction with the adjacent phosphorus atom.

• 出版日期2009