(Heptanedioato-kappa O-2,O ')bis(1,10-phenan-throline-kappa N-2,N ')zinc(II) hexahydrate

作者:Lin Jian Li*; Wang Yuan Yuan
来源:Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M527-U169.
DOI:10.1107/S1600536808006004

摘要

In the crystal structure of the title compound, [Zn(C7H10O4)-(C12H8N2)(2)]center dot 6H(2)O, the Zn-II atom is coordinated by two carboxylate O atoms of a mono-bidentate chelating pimelate anion ( pimelic acid is heptanedioic acid) and four N atoms of two phenanthroline ligands, forming a considerably distorted octahedral ZnN4O2 coordination geometry. The complexes are assembled into a three-dimensional network via C-H center dot center dot center dot O, C-H center dot center dot center dot pi and pi-pi interactions. The mean interplanar distance between adjacent phenanthroline ligands is 3.399 (2) angstrom.