A 3D 12-Ring Zeolite with Ordered 4-Ring Vacancies Occupied by (H2O)(2) Dimers

作者：Liang Jie; Su Jie; Wang Yingxia^*; Chen Yanping; Zou Xiaodong; Liao Fuhui; Lin Jianhua; Sun Junliang

来源：Chemistry - A European Journal, 2014, 20(49): 16097-16101.

DOI：10.1002/chem.201405449

• electron microscopy
• porous materials
• structure elucidation
• zeolite analogues
• X-ray diffraction

A germanate zeolite, PKU-14, with a three- dimensional large-pore channel system was structurally characterized by a combination of high-resolution powder X-ray diffraction, rotation electron diffraction, NMR, and IR spectroscopy. Ordered Ge4O4 vacancies inside the [4(6).6(12)] cages has been found in PKU-14, in which a unique (H2O)(2) dimer was located at the vacancies and played a structure-directing role. It is the first time that water clusters are found to be templates for ordered framework vacancies.

• 出版日期2014-12-1
• 单位北京大学