Autoxidation of thiol-containing amino acid to its disulfide derivative that links two copper(II) centers: the important role of auxiliary ligand

作者：Seko Hiroyuki; Tsuge Kiyoshi; Igashira Kamiyama Asako; Kawamoto Tatsuya; Konno Takumi^*

来源：Chemical Communications, 2010, 46(11): 1962-1964.

DOI：10.1039/b913989c

Treatment of Cu(AcO)(2) with D-penicillamine or L-cysteine in the presence of 2,2'-bipyridine afforded dicopper(II) complexes with a bis(bidentate-N,O) disulfide ligand, the formation mechanism of which was discussed on the basis of Cu(II)-thiolate interaction affected by an auxiliary ligand.

• 出版日期2010