A three-dimensional network of two-electron-transferred [Ru-2](2)TCNQ exhibiting anomalous conductance due to charge fluctuations

作者：Miyasaka Hitoshi^*; Morita Takaumi; Yamashita Masahiro

来源：Chemical Communications, 2011, 47(1): 271-273.

DOI：10.1039/c0cc02031a

A new D(2)A-type charge-transfer three-dimensional network with a charge distribution of [{Ru-2}(delta+)-(BTDA-TCNQ(2 delta-))-{Ru-2}(delta+)] where delta approximate to 1, which exhibits a sudden decrease in electronic resistance, formed from the assembly of a paddlewheel diruthenium(II, II) complex ([Ru-2]) as a donor (D) and bis(1,2,5-thiadiazolo)tetracyanoquinodimethane (BTDA-TCNQ) as an acceptor (A).

• 出版日期2011