Pyridinium-clubbed dicationic ionic liquid electrolytes for efficient next-generation photo harvesting

作者：Dhar Abhishek; Kumar Nadavala Siva; Asif Mohammad; Vekariya Rohit L^*

来源：New Journal of Chemistry, 2018, 42(9): 6990-6996.

DOI：10.1039/c8nj00330k

We have developed a new series of pyridinium based dicationic ionic liquids (DCILs) having excellent thermal stability and good ionic conductivity. The effectiveness of these DCIL based electrolytes in photovoltaic devices and the effect of different anions (e.g. iodine, bromide, and thiocyanate) versus the device performance are studied by cyclic voltammetry (CV), current-voltage (I-V) characteristics and electrochemical impedance spectroscopy (EIS). The electrolyte 2PrSCN based device C exhibited the highest photo conversion efficiency (PCE) of 5.23% under 1 sun (100 mW cm(-2)) illumination of light. We have also analyzed the influence of various anions in metal-free dye-sensitized TiO2 and the DCIL interface using the EIS technique. Device C based on 2PrSCN shows excellent long-term stability, maintaining <95% of the initial efficiency after 500 h.

• 出版日期2018-5-7