New Strongly Correlated One-Dimensional Organic Semiconductor (ChTM-TTP)(2)Ag(CN)(2)

作者:Kawamoto Tadashi*; Ashizawa Minoru; Mori Takehiko
来源:Bulletin of the Chemical Society of Japan, 2013, 86(4): 526-528.
DOI:10.1246/bcsj.20120292

摘要

Crystal structure, transport, and magnetic properties of a new organic conductor (ChTM-TTP)(2)Ag(CN)(2), where ChTM-TTP is 244,5-(1,2-cyclohexylenedithio)-1,3-dithiol-2-ylidene] -544,5-bis(methylthio)-1,3-dithiol-2-ylidene]-1,3,4,6-tetrathiapentalene, have been studied. Although the crystal structure is similar to metallic ChTM-TTP conductors, the present compound is a paramagnetic semiconductor even at room temperature, indicating strongly electron correlation.

  • 出版日期2013-4-15