A New Class of C-3-Symmetrical Hemicryptophane Hosts: Triamide- and Tren-hemicryptophanes

作者:Raytchev Pascal Dimitrov; Perraud Olivier; Aronica Christophe; Martinez Alexandre*; Dutasta Jean Pierre
来源:Journal of Organic Chemistry, 2010, 75(6): 2099-2102.
DOI:10.1021/jo100052r

摘要

The first hemicryptophanes derived from tris(N-alkyl-carbamoylmethyl)amine and tris(2-aminoethyl)amine (tren) have been synthesized following a single synthetic pathway that allows the subsequent formation of the two heteroditopic hosts 3 and 4. X-ray crystal Structures show a well-defined cavity encapsulating a solvent guest for both compounds emphasizing their complexation properties.

  • 出版日期2010-3-19