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摘要
The dimeric, tetranuclear manganese(II)-substituted sandwich-type phosphotungstate complex has been synthesized in high yield using a straightforward one-pot synthesis by reacting commercially available H-3[PW12O40] with MnCl2. The complex has been characterized by single-crystal X-ray structure analysis. The complex is oxidatively and solvolytically stable and has been used as a heterogeneous catalyst in the efficient, selective aerobic epoxidation of styrene, cyclohexene and cis-cyclooctene.
- 出版日期2011-4
