Dual catalysis: new approaches for the polymerization of lactones and polar olefins

作者:Piedra Arroni Estefana; Amgoune Abderrahmane*; Bourissou Didier
来源:Dalton Transactions, 2013, 42(25): 9024-9029.
DOI:10.1039/c3dt00074e

摘要

Recently catalytic systems combining Al, In or Zn Lewis acids with organic bases (amines, phosphines, N-heterocyclic carbenes) have been shown to efficiently promote the polymerization of lactones and polar olefins. In this frontier article, such dual approaches of polymerization catalysis are presented. Special attention is devoted to the mode of action of the dual systems and the underlying cooperative effects.

  • 出版日期2013