A Water-Stable Anionic Metal Organic Framework Constructed from Columnar Zinc-Adeninate Units for Highly Selective Light Hydrocarbon Separation and Efficient Separation of Organic Dyes

作者：Ma, Hui -Fang; Liu, Qing-Yan^*; Wang, Yu -Ling^*; Yin, Shun-Gao

来源：Inorganic Chemistry, 2017, 56(5): 2919-2925.

DOI：10.1021/acs.inorgchem.6b03026

• ZEOLITIC IMIDAZOLATE FRAMEWORKS
• CARBON-DIOXIDE CAPTURE
• ADSORPTION PROPERTIES
• HYSTERETIC SORPTION
• HYDROGEN ADSORPTION
• GAS-ADSORPTION
• STABILITY
• MOF
• CO2
• TOPOLOGY

A metal-organic framework (MOF), {(Me2NH2)(2)[Zn-6(mu(4)-O)(ad)(4)(BPDC)(4)]}n (JXNU-4; ad- = adeninate), with an anionic three-dimensional (3D) framework constructed from one-dimensional (1D) columnar [Zn-6(ad)(4)(mu(4)-O)]n secondary building units (SBUs) and 4,4'-biphenyldicarboxylate (BPDC2-) ligand, was prepared. The anionic 3D framework has 1D square channels with an aperture of about 9.8 angstrom and exhibits a carboxylate-O-decorated pore environment. The microporous nature of JXNU-4 was established by the N-2 adsorption data, which gives Langmuir and Brumauer-Emmett-Teller surface areas of 1800 and 1250 m(2) g(-1), respectively. Noticeably, JXNU-4 shows potential as a separation agent for the selective removal of propane and ethane from natural gas with high selectivities of 144 for C3H8/CH4 (5:95) and 14.6 for C2H6/CH4 (5:95), respectively. Most importantly, JXNU-4 shows an aqueous-phase adsorption of a positively charged ion of methylene blue selectively over a negatively charged ion of resorufin, which is pertinent to the anionic nature of the framework, and provides a size-exclusive sieving of methylene blue over other positively charged ions of Janus Green B and ethyl violet, which is relevant to its pore structure, enabling the efficient aqueous-phase separation of organic dyes.

• 出版日期2017-3-6
• 单位江西师范大学