Dehydration of bacterial cellulose and the water content effects on its viscoelastic and electrochemical properties

作者:Rebelo, Ana R.; Archer, Andrew J.; Chen, Xiuli; Liu, Changqing; Yang, Guang; Liu, Yang*
来源:Science and Technology of Advanced Materials, 2018, 19(1): 203-211.
DOI:10.1080/14686996.2018.1430981

摘要

Bacterial cellulose (BC) has interesting properties including high crystallinity, tensile strength, degree of polymerisation, water holding capacity (98%) and an overall attractive 3D nanofibrillar structure. The mechanical and electrochemical properties can be tailored upon incomplete BC dehydration. Under different water contents (100, 80 and 50%), the rheology and electrochemistry of BC were evaluated, showing a progressive stiffening and increasing resistance with lower capacitance after partial dehydration. BC water loss was mathematically modelled for predicting its water content and for understanding the structural changes of post-dried BC. The dehydration of the samples was determined via water evaporation at 37 degrees C for different diameters and thicknesses. The gradual water evaporation observed was well-described by the model proposed (R-2 up to 0.99). The mathematical model for BC water loss may allow the optimisation of these properties for an intended application and may be extendable for other conditions and purposes. @@@ [GRAPHICS] @@@ .